Publications

Publications by year

 

2019

 

Improvement of the ionic conductivity on new substituted borohydride argyrodites.

Dao A.-H., Lopez-Aranguren P., Cerny R., Guiader O., Zhang J., Cuevas F., Latroche M., Jordy Ch.

Solid State Ionics (2019), 339, 114987

Hydrated and anhydrous dodecahydro closo-dodecaborates of 3d transition metals and of magnesium.

Didelot E., Sadikin Y., Lodziana Z. and Cerny R.

Solid State Sciences (2019), 90, 86-94

Mixed-Metal Imidazolates Containing Alkali and Alkaline Earth Metals: Mechanochemical Synthesis and Crystal Structure of AMgIm3 (A=Na or K)

Burazer S., Morelle F., Filinchuk Ya., Cerny R., Popovic J.

Inorg. Chem. (2019), 58, 6927-6933

 

2018

A mixed anion hydroborate/carba-hydroborate as a room temperature Na-ion solid electrolyte
Brighi M., Murgia F., Lodziana Z., Schouwink P., Wolczyk A. and Cerny R.
J. Power Sources (2018), 404, 7-12

New phases in the Rb-Mg-N-H and Rb-N-H systems: a structural characterization
A. Santoru, C. Pistidda, M. Brighi, M.R. Chierotti, M. Heere, F. Karimi, H. Cao, G. Capurso, G. Gizer, S. Garroni, J. Puszkiel, M.H. Sørby, B.C. Hauback, P. Chen, R. Cerny, T. Klassen and M. Dornheim
Inorg. Chem. (2018), 57, 3197-3205

Synthesis and crystal structure of solvent-free dodecahydro closo-dodecaborate of nickel, NiB12H12.
Sadikin Y., Didelot E., Lodziana Z. and Cerny R.
Dalton Trans. (2018), 47, 5843-5849

 

2017

 

Solid Aluminum Borohydrides as Perspective Hydrogen Stores.
Dovgaliuk I., Safin D., Tumanov N., Morelle F., Cerny R., Lodziana Z., Devillers M. and Filinchuk Ya.
ChemSusChem (2017), 10, 4725-4734

An innovative in situ ball mill for X-ray diffraction
Ban V., Sadikin Y., Lange M., Tumanov N., Filinchuk Y., Cerny R. and Casati N.
Analyt. Chemistry (2017), 89, 13176-13181

Rapid synthesis of MgB2 by inductive heating
Matera D., Bonura M., Barth C., Fête A., Cerny R., Giannini E. and Senatore C.
IEEE Trans. Applied Supracond. (2017), 28, no. 4, 6200405

Synthesis, structure and properties of bimetallic sodium rare earth (RE) borohydrides, NaRE(BH4)4, RE = Ce, Pr, Er or Gd.
Payandeh GharibDoust S.H., Ravnsbaek D.B., Cerny R. and Jensen T.R.
Dalton Trans. (2017), 46, 13421-13431

Synthesis, structure and Li-ion conductivity of LiLa(BH4)3X, X = Cl, Br, I.
Payandeh GharibDoust S.H., Brighi M., Sadikin Y., Ravnsbaek D., Cerny R., Skibsted J. and Jensen T.R.
Phys. Chem. C (2017), 121, 19010-19021

Variation of Tc, lattice parameter and atomic ordering in Nb3Sn platelets irradiated with 12 MeV protons: correlation with the number of induced Frenkel defects.
R. Flükiger, T. Spina, F. Cerutti, A. Ballarino, C. Scheuerlein, L. Bottura, Y. Zubavichus, A. Ryazanov, S. Shavkin, P. Degtyarenko, Y. Semenov, C. Senatore and R. Cerny
Superconductor Science and Technology (2017) 30, 054003

FOX, current state and possibilitites.
Cerny R., Favre-Nicolin V., Rohlicek J. and Husak M.
Crystals (2017), 7, 322,

Solid Aluminum Borohydrides as Perspective Hydrogen Stores.
Dovgaliuk I., Safin D., Tumanov N., Morelle F., Cerny R., Lodziana Z., Devillers M. and Filinchuk Ya.
ChemSusChem (2017), in press,

Modified anion packing of Na2B12H12 in close to room temperature superionic conductors.
Sadikin Y., Schouwink P., Brighi M., Lodziana Z. and Cerny R.
Inorg. Chem. (2017), 56, 5006-5016,

Ionic conduction in bimetallic borohydride borate, LiCa3(BH4)(BO3)2.
Didelot E. and Cerny R.
Solid State Ionics (2017), 305, 16-22,

Li5(BH4)3NH, lithium rich mixed anion complex hydride.
Wolczyk A., Paik B., Sato T., Nervi C., Brighi M., Payandeh GharibDoust S.H., Chierotti M., Matsuo M., Li G., Gobetto R., Jensen T., Cerny R. Orimo S.-I. and Baricco M.
Phys. Chem. C. (2017), 121 (21), 11069-11075

Hydrogen sorption in erbium borohydride composite mixtures with LiBH4 and/or LiH.
Heere M., Payandeh GharibDoust S.H., Brighi M., Frommen Ch., Sørby M.H., Cerny R., Jensen T.R. and Hauback B.C.
Inorganics (2017),

Crystal structures from powder diffraction: principles, difficulties and progress.
Cerny R.
Crystals (2017), 7, 142,

Metal borohydrides and derivatives – synthesis, structure and properties.
Paskevicius M., Jepsen L.H., Schouwink P., Cerny R., Ravnsbaeck D., Filinchuk Y., Dornheim M., Besenbacher F. and Jensen T.R.
Chem. Soc. Rev. (2017), 46, 1565-1634,

Anion disorder in K3BH4B12H12 and its effect on cation mobility.
Sadikin Y., Skoryunov R.V., Babanova O.A., Soloninin A.V., Lodziana Z., Brighi M., Skripov A.V. and Cerny R.
J. Phys. Chem. C. (2017), 121, 5503-5514

2016

Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydrides.
Payandeh GharibDoust S.H., Heere M., Sorby M., Brix Ley M.,Ravnsbaek D.B., Hauback B.,Cerny R. and Jensen T.R.
Dalton Trans. (2016), 45, 19002

From M(BH4)3 (M = La, Ce) borohydride frameworks to controllable synthesis of ion conductors.
Brix Ley M., Jorgensen M., Cerny R., Filinchuk Y. and Jensen T.R.
Inorg. Chem. 55 (2016) 9748–9756

Halide free M(BH4)2 (M=Sr, Ba, Eu) synthesis, structure and decomposition.
Sharma M., Didelot E., Spyratou A., Lawson Daku L.M., Cerny R. and Hagemann H.
Inorg. Chem. 55 (2016) 7090-7097


Synthesis and thermal stability of perovskite alkali metal strontium borohydrides
K. T. Møller, M. B. Ley, P. Schouwink, R. Černý, T. R. Jensen
Dalton Trans. 45 (2016) 831-840


High-Pressure Study of Mn(BH4)2 Reveals a Stable Polymorph with High Hydrogen Density
N. A. Tumanov, E. Roedern, Z. Łodziana, D. B. Nielsen, T. R. Jensen, A. V. Talyzin, R. Černý, D. Chernyshov, V. Dmitriev, T. Palasyuk, Y. Filinchuk
Chem. Mater. 28 (2016) 274–283


Fast ion conduction in garnet-type metal borohydrides Li3K3Ce2(BH4)12 and Li3K3La2(BH4)12
M. Brighi, P. Schouwink, Y. Sadikin, R. Černý
J. Allloys Compd. 662 (2016) 388–395


Structural and magnetocaloric properties of novel gadolinium borohydrides
P. Schouwink, E. Didelot, Y.-S. Lee, T. Mazet, R. Černý
J. Allloys Compd. 664 (2016) 378–384


Jahn-Teller induced nematic orbital order in tetragonal Sr2VO4
J. Teyssier, E. Giannini, A. Stucky, R. Černý, M. V. Eremin, D. van der Marel
Phys. Rev. B 93 (2016) 125138

 

2015

Di-hydrogen contact induced lattice instabilities and structural dynamics in complex hydride perovskites
Schouwink P., Hagemann H., Embs J. P, D’Anna V. and Cerny R.
J. Phys. Condens. Matt., 27 (2015) 265403

Flux-assisted single crystal growth and heteroepitaxy of perovskite-type mixed metal borohydrides
Schouwink P., Ramel A., Giannini, E. and Cerny R.
CrystEngComm, 17 (2015) 2682-2689

Isotope Exchange Reactions in Ca(BH4)2
Sharma M., Sethio D., D’Anna V., Fallas J.C., Schouwink P., Cerny R. and Hagemann H.
J. Phys. Chem. C, 119 (2015) 29–32

Alkali metal – yttrium borohydrides: The link between coordination of small and large rare-earth
Sadikin Y., Stare K., Schouwink P., Brix Ley M., Jensen T.R., Meden A. and Cerny R.
J. Solid State Chem, 225 (2015) 231–239

Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate
Huang J., Tan Y., Su J., Gu Q., Cerny R., Ouyang L., Sun D., Yu X., Zhu M.
Chem. Comm., 51 (2015) 2794-2797

Experimental observation of polymerization from BH4– to B12H122− in mixed-anion A3BH4B12H12 (A = Rb+, Cs+)
Schouwink, P., Sadikin, Y., van Beek, W., Cerny, R.
Int. J. Hydrogen. Energ., 40 (2015) 10902-10907

Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy)
Jepsen, L. H., Ley, M. B., Cerny, R., Lee, Y. S., Cho, Y. W., Ravnsbaek, D., Besenbacher, F., Skibsted, J., Jensen, T. R.
Inorg. Chem., 54 (2015) 7402-7414

Increasing Hydrogen Density with the Cation-Anion Pair BH4−-NH4+ in Perovskite-Type NH4Ca(BH4)3
Schouwink, P., Morelle, F., Sadikin, Y., Filinchuk, Y., Cerny, R.
Energies, 8 (2015) 8286-8299

Nuclear Magnetic Resonance Study of Atomic Motion in Bimetallic Perovskite-Type Borohydrides ACa(BH4)3 (A = K, Rb, or Cs)
Skoryunov, R. V., Soloninin, A. V., Babanova, O. A., Skripov, A. V., Schouwink, P., Cerny, R.
J. Phys. Chem. C (2015), DOI: 10.1021/acs.jpcc.5b06540

Superionic Conduction of Sodium and Lithium in Anion-Mixed Hydroborates Na3BH4B12H12 and (Li0.7Na0.3)3BH4B12H12
Sadikin, Y., Brighi, M., Schouwink, P., Cerny, R.
Adv. Energ. Mater. (2015), DOI: 10.1002/aenm.201501016

Ammine Calcium and Strontium Borohydrides: Syntheses, Structures, and Properties
Jepsen, L., Lee, Y.-S., Černý, R., Sarusie, R. S., Cho, Y. W., Besenbacher, F., Jensen, T. R.
ChemSusChem (2015), DOI: 10.1002/cssc.201500713

Pearson’s Crystal Data – Crystal Structure Database for Inorganic Compounds, Edition 2015/16 (off-line product)
Villars P., Cenzual K. (Eds.)
ASM International, Materials Park, Ohio-USA

Handbook of Inorganic Substances 2016 (handbook, e-book)
Villars P., Cenzual. K., Gladyshevskii R. (Eds.), De Gruyter, Berlin, Germany
Handbook of Inorganic Substances 2016

Inorganic Substances Bibliography 2016 (e-book)
Villars P., Cenzual K., Penzo M. (Eds.), De Gruyter, Berlin, Germany
Inorganic Substances Bibliography 2016

Alloy Phase Diagram Database (on-line product, yearly updates)
Villars P. (editor-in-chief), Okamoto H. (constitution), Cenzual K. (structures), ASM International, Materials Park, Ohio-USA
Alloy Phase Diagram Database

SpringerMaterials: Inorganic Solid Phases
Villars P. (chief editor), Cenzual K., Hulliger F., Iwata S., Okamoto H.
SpringerMaterials

The crystal chemistry of inorganic metal boro­hydrides and their relation to metal oxides
Černý, R., Schouwink, P.
Acta Cryst B (2015), DOI: 10.1107/S2052520615018508

Preparation of Anisotropic and Oriented Particles on a Flexible Substrate
M. Chekini, U. Cataldi, P. Maroni, Laure Guénée, Černý, R., T. Bürgi
Langmuir, 31 (2015) 13221-13229

 

2014

Complex Hydrides – When Powder Diffraction needs Help
Schouwink P. and Cerny R.
Chimia, 68 (2014) 1/2, 38-44

Role of the Li+ node in the Li-BH4 substructure of double-cation tetrahydroborates
Schouwink P., Smrcok L. and Cerny R.
Acta Cryst. B, 70 (2014) 871-878

The First Halide-Free Bimetallic Aluminum Borohydride: Synthesis, Structure, Stability, and Decomposition Pathway
Dovgaliuk I., Ban V., Sadikin Y., Cerny R., Aranda L., Casati N., Devillers M. and Filinchuk Y.
J. Phys. Chem. C, 118 (2014) 145–153

Tb2Al3Ge3, a New Partly Disordered Structure Type with Al3 Triangles
Gladyshevskii R., Lutsyshyn Yu., Cerny R. and Cenzual K.
Z. Anorg. Allg. Chem., 640 (2014) 2512–2519

Borohydrides: From Sheet to Framework Topologies
Schouwink P., Brix Ley M., Jensen T.R., Smrcok L. and Cerny R.
Dalton. Trans., 43 (2014) 7726-7733

Structure and properties of perovskite-type complex metal hydrides.
Schouwink P., Brix Ley M., Tissot A., Hagemann H., Jensen T.R., Smrcok L. and Cerny R.
Nature Comm., 5 (2014) 5706

 

2013

The first transition metal iodato peroxido complex: the synthesis, vibrational spectra and crystal structure from pwoder diffraction data of K3[V2O2(O2)4(IO3)] H2O
Simunekova M., Schwendt P., Chrappova J., Smrcok L., Cerny R. and van Beek W.
C. Eu. J. Chem., 11 (2013) 1352-1359

A modulated structure derived from the sigma phase in the Mo-Ni-Re system.
Yaqoob K., Guénée L., Cerny R. and Joubert J.M.
Intermetallics, 37 (2013) 42-45

Impact of hydrogen absorption on crystal structure and magnetic properties of geometrically frustrated Nd2Ni2In.
Mašková S., Havela L., Daniš S., Llobet A., Nakotte H., Kothapalli K., Cerny R. and Kolomiets A.
J. Alloys and Compd., 566 (2013) 22-30

Hydrogen absorption in RE2T2In compounds.
Mašková S., Kolomiets A., Havela L., Andreev A.V., Svoboda P., Nakotte H. and Cerny R.
J. Alloys and Compd., 580 (2013) S105–S108

Trimetallic borohydride Li3MZn5(BH4)15 (M = Mg, Mn), two weakly
interconnected frameworks.
Cerny R., Schouwink P., Sadikin Y., Stare K., Smrcok L., Richter B. and Jensen T.R.
Inorg. Chem., 52 (2013) 9941-9947, dx.doi.org/10.1021/ic401139k

Novel alkali earth borohydride Sr(BH4)2, and borohydride-chloride Sr(BH4)Cl.
Ravnsbaek D.B., Nickels E.A., Cerny R., Olesen C.H., David W.I.F., Edwards P.P., Filinchuk Y., and Jensen T.
Inorg. Chem., 52 (2013) 10877-10885

Effect of pressure cycling on iron: Signatures of an electronic instability and unconventional superconductivity.
Yadav C.S., Seyfarth G., Pedrazzini P., Wilhelm H., Cerny R. and Jaccard D.
Phys. Rev. B, 88 (2013) 054110

Crystal structure solution of an elusive polymorph of Dibenzylsquaramide.
Portell A., Alcobé X., Lawson Daku L.M., Cerny R. and Prohens R.
Powder Diffr., 28 (2013) S470-S480

 

2012

Potassium zinc borohydrides containing triangular [Zn(BH4)3]- and tetrahedral [Zn(BH4)xCl4-x]2- anions.
Cerny R., Ravnsbæk D., Schouwink P., Filinchuk Y., Penin N., Teyssier J., Smrcok L. and Jensen T.R.
J. Phys. Chem. C, 116 (2012) 1563-1571

New CeMgCo4 and Ce2MgCo9 compounds: hydrogenation properties and crystal structure of hydrides.
Denys R.V., Riabov A., Cerny R., Koval’chuk I.V. and Zavaliy I.Yu.
J. Solid State Chem., 187 (2012) 1-6

Bimetallic borohydrides in the system M(BH4)2 – KBH4 (M=Mg, Mn): On the structural diversity.
Schouwink P., D’Anna V., Brix Ley M., Lawson Daku L.M., Richter B., Jensen T.R., Hagemann H. and Cerny R.
J. Phys. Chem. C, 116 (2012) 10829-10840

Mechano-chemical synthesis of manganese borohydride (Mn(BH4)2) and inverse cubic spinel Li2MnCl4 in the (nLiBH4+MnCl2) (n=1,2,3,5,9 and 23) mixtures and their dehydrogenation behavior..
Varin R.A., Zbroniec L., Polanski M., Filinchuk Y. and Cerny R.
Int. J. Hydrogen Energy, 37 (2012) 16056–16069

 

2011

New fundamental Experimental Studies on alpha-Mg(BH4)2 and other borohydrides.
Hagemann H., D’Anna V., Rapin J.P., Cerny R., Filinchuk Y., Ki Chul Kim, Sholl. D.S. and Parker S.F.
J- Alloys. Compd., 509S (2011) S688-S690

Novel sodium aluminium borohydride containing the complex anion Al(BH4,Cl)4.
Lindemann I., Ferrer R.D., Dunsch L., Cerny R., Hagemann H., D’Anna V., Filinchuk Y., Schultz L. and Gutfleisch O.
Faraday Discussions, 151 (2011) 231-242

Crystal chemistry, superconductivity and magnetism in iron chalcogenides.
Giannini E., Viennois R., Cerny R. and Hanfland M.
Chem. Met. Alloys , 3 (2011) 63-68

“Post-hydrogenation” structural transformation from KHg2- to Fe2P-type in R(Cu,Ni)2 hydrides (R=Ce, Pr, Nd).
Riabov A., Denys R., Cerny R. and Zavaliy I.Yu.
Chem. Met. Alloys , 3 (2011) 169-176

MgxMn(1-x)(BH4)2 (x=0-0.8), cation solid solution in a bimetallic borohydride.
Cerny R., Penin N., D’Anna V., Hagemann H., Durand E. and Ruzicka J.
Acta Materialia, 59 (2011) 5171-5180

Mitigation of hydrogen capacity losses during pressure cycling of the Li3N-H system by the addition of nitrogen.
Lamb J.,Chandra D., Chien W.-M., Phanon D., Penin N., Cerny R. and Yvon K.
J. Phys. Chem. C, 115 (2011) 14386-14391

Crystal Structures of CaLa8Ti9O31 and Ca2La4Ti6O20 Determined from Powder Diffraction Data.
Stare K., Cerny R., Skarpin S.D., Souvorov D. and Meden A.
Acta Chimica Slovenica, 58 (2011)465-470 .

Local deuterium order in apparently disordered Laves phase deuteride YFe2D4.2
Ropka J., Cerny R. and Paul-Boncour V.
J. Solid State Chem., 184 (2011) 2516-2524

Crystal structure of the novel Mg3MnNi2D3-x interstitial deuteride.
Denys R.V., Riabov A., Berezovets V.V., Koval’chuk I.V., Cerny R. and Zavaliy I.Yu.
Intermetallics, 19 (2011) 1563-1566

Complex inorganic structures from powder diffraction: case of tetrahydroborates of light metals.
Cerny R. and Filinchuk Y.
Z. Kristallogr., 226 (2011) 882-891

2010

Phase diagram of single-crystalline tetragonal iron chalcogenides
Viennois R., Giannini E., van der Marel D. and Cerny R.
Physica C, 470 (2010) S370-S371

Lapeyreite, Cu3O[AsO3(OH)]2.0.75H2O, a new mineral: its description and crystal structure.
Sarp H., Cerny R., Babalik H., Hatipoglu M. and Mari G.
American Mineralogist, 95 (2010) 171-176

Crystal structures of three intermetallic phases in the Mo-Pt-Si system
Joubert J.-M., Tokaychuk Y. and Cerny R.
J. Solid State Chem., 183 (2010) 173–179

K3TaF8 from laboratory X-ray powder data.
Smrcok L., Cerny R., Boca M., Mackova I. and Kubikova B.
Acta Cryst. C., 66 (2010) i16-i18

NaSc(BH4)4 : A novel scandium-based borohydride
Cerny R., Severa G. , Ravnsbæk D., Filinchuk Y., D’Anna V., Hagemann H., Haase D., Jensen C.M.and Jensen T.R.
J. Phys. Chem. C, 114 (2010) 1357-1364

Pseudo-tetragonal structure of Li2+xCeIIIxCeIV12-xF50.
Renaudin G., Dieudonné B., Avignant D., Mapemba E., El-Ghozzi M., Fleutot S., Martinez H., Cerny R. and Dubois M.
Inorg. Chem., 94 (2010) 686-694

Effect of Fe excess on structural and magnetic properties of single-crystalline Fe(1+x)Te(1-y)Se(y)
Viennois R., Giannini E., van der Marel D. and Cerny R.
J. Solid State Chem., 183 (2010) 769-775

Thermal polymorphism and decomposition of Y(BH4)3
Ravnsbæk D., Filinchuk Y., Cerny R., Ley M.B., Haase D., Jakobsen H.J., Skibsted J. and Jensen T.R.
Inorg. Chem., 49 (2010) 3801-3809

A density functional theory investigation of Li4NH and Li1.5NH1.5, as intermediary compounds during hydrogenation of Li3N.
Crivello J.-C., Gupta M., Cerny R., Latroche M. and Chandra D.
Phys. Rev. B, 81 (2010) 104113

Synthetic approaches to inorganic borohydrides
Hagemann H. and Cerny R.
Dalton Trans., 39 (2010) 6006-6012

Al3Li4(BH4)13 a new double-cation borohydride with a novel structure.
Lindemann I., Ferrer R.D., Dunsch L., Filinchuk Y., Cerny R., Hagemann H., D’Anna V., Lawson Daku M.L., Schultz L. and Gutfleisch O.
Chem. Eur. J., 16 (2010) 8707 – 8712

Li3-xMxN (M = Co, Ni) synthesized by Spark Plasma Sintering for hydrogen storage.
Junxian Zhang, Cerny R., Villeroy B., Godart C., Chandra D. and Latroche M.
J. Alloys Compd., 509S (2010) S732-S735

AZn2(BH4)5 (A = Li, Na) and NaZn(BH4)3: structural studies.
Cerny R., Ki Chul Kim, Penin N., D’Anna V., Hagemann H. and Sholl D.S.
J. Phys. Chem. C, 114 (2010) 19127-19133

Structure and characterization of KSc(BH4)4.
Cerny R., Ravnsbæk D., Severa G. , Filinchuk Y., D’Anna V., Hagemann H., Haase D., Skibsted J., Jensen C.M.and Jensen T.R.
J. Phys. Chem. C, 114 (2010) 19540-19549

Powder diffraction methods for studies of borohydride-based energy storage materials.
Ravnsbæk D., Filinchuk Y., Cerny R. and Jensen T.R.
Z. Kristallogr., 225 (2010) 557-569

2000 to 2009

Réalisation : Sur Mesure concept